(3R,4R,6S)-4-{[Dimethyl(2-Methyl-2-Propanyl)Silyl]Oxy}-6-Methyl-3-(2-Oxopropyl)Tetrahydro-2H-Pyran-2-One

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Properties Simple | Detailed

Formula C15H28O4Si
IUPAC Name (3r,4r,6s)-3-acetonyl-4-[tert-butyl(dimethyl)silyl]oxy-6-methyl-tetrahydropyran-2-one
Molecular Mass 300.466 g·mol−1
Heat of Formation -1081.7 ± 16.7 kJ·mol−1
Dipole Moment 3.38 ± 1.08 D
Volume 400.94 Å 3
Surface Area 313.01 Å 2
HOMO Energy -9.86 ± 0.55 eV
LUMO Energy 0.91 ± eV
Point Group Symmetry C1
Synonyms
  • (+)(-)-(3alpha,4alpha,6alpha)-4-(tert-butyldimethylsiloxy)-3,4,5,6-tetrahydro-6-methyl-3-(2-oxopropyl)-2h-pyran-2-one
  • (3r,4r,6s)-3-acetonyl-4-(tert-butyl-dimethyl-silyl)oxy-6-methyl-tetrahydropyran-2-one
  • (3r,4r,6s)-3-acetonyl-4-(tert-butyl-dimethylsilyl)oxy-6-methyl-2-tetrahydropyranone
  • (3r,4r,6s)-4-(tert-butyl-dimethyl-silyl)oxy-6-methyl-3-(2-oxopropyl)oxan-2-one
  • (3r,4r,6s)-4-(tert-butyl-dimethylsilyl)oxy-6-methyl-3-(2-oxopropyl)oxan-2-one
  • 2h-pyran-2-one, 4-(((1,1-dimethylethyl)dimethylsilyl)oxy)tetrahydro-6-methyl-3-(2-oxopropyl)-, (3alpha,4alpha,6alpha)-(+-)-
  • 4-(tert-butyldimethylsiloxy)-3,4,5,6-tetrahydro-6-methyl-3-(2-oxopropyl)-2h-pyran-2-one
  • bdms-mop-pyran
CAS Number(s)
  • 125119-52-0
InChIKey FNUOFCVBBCWIRG-YNEHKIRRSA-N
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Elements H Si C O